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Prof. P. A. Christensen

 

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Updated: 28 Jan 09

 

 

PolyChlorinated Biphenyls or PCBs:

Structure of polychlorinated biphenyls

  • A group of 209 individual chlorinated biphenyls (‘congeners’) with the positions 1 - 6 and 1' - 6' on the two rings occupied by chlorine atoms.
  • Were typically manufactured as mixtures of 60 to 90 different congeners
  • Highly toxic
  • Used as dielectrics, coolants and lubricants in electrical transformers and other electrical equipment, weatherproofers, and to prolong residual activity of pesticides. Usually released to the environment as a mixture in which other chemicals are also present.
  • In the concentrated form, PCBs are either oily liquids or waxy solids with no discernable taste or odor.
  • As the number of chlorines in a PCB mixture increases the flash point rises and the substance becomes less combustible. Also, PCBs with large numbers of chlorines are more stable and thus resistant to biodegradation.
  • The most highly favored PCBs tended to be the ones with large numbers of chlorines: these congeners are also proving to be the ones that present the greatest environmental and health risks.

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